具有凝胶外壳金纳米管的可调节近红外光声转换效率
Tunable photoacoustic efficiency in infrared of gold nanotubes with gel shells
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摘要: 采用有限元方法建立了金属纳米颗粒的光声效应模型,可计算近红外光脉冲激励下不同颗粒的声信号随时间的变化特性。文中以包裹凝胶壳的金纳米管为例,研究凝胶外壳对声压信号的影响,指出凝胶壳能够有效提高金纳米管声压信号幅度,声信号最大可增长至包裹前的6倍左右。进一步研究表明,为获取最强声信号,必须调整金纳米管的结构参数使其表面等离激元共振波长与入射脉冲激光波长相匹配。本工作可以为红外光声造影剂的设计提供参考。Abstract: Numerical photoacoustic models were constructed to study photoacoustic signals from metal nano-particles under pulse excitation in infrared based on the finite element algorithm.Gold nanotubes with gel shells were taken as the example to investigate the influence of gel shells on the acoustic signals.The gel shell can promote the signal greatly and the maximum one is about 6 times of that from naked nanotubes.It is also found that the strongest acoustic signal can be got only if the structural parameters of the nanotubes are tuned to make the surface plasmon resonance match with the incident light.This work can serve as a reference for the infrared photoacoustic contrast agents.