超声波和紫外光协同降解酸性橙Ⅱ水溶液的机理研究
Study of the synergistic effects on degradation of acid orange Ⅱ solution under combined irradiation of ultrasound and ultraviolet light
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摘要: 以含有多个苯环的典型偶氮染料-酸性橙Ⅱ为研究对象,研究了超声波和紫外光分别辐照及共同辐照下的降解现象。酸性橙Ⅱ水溶液在超声波及紫外光分别辐照下均发生显著降解,反应过程符合准一级反应动力学规律。在超声波和紫外光共同辐照下,反应过程也符合准一级反应动力学规律,同时酸性橙Ⅱ水溶液降解呈现显著的声光协同效应,即同一辐照时间内超声波和紫外光共同辐照下酸性橙Ⅱ的降解率大于超声波和紫外光单独辐照下各自降解率之和。动力学分析结果表明,该协同效应可归因于紫外光对超声空化过程中产生的过氧化氢的裂解作用。Abstract: The typical azo dyes acid orangeⅡ(AO7),which contains several benzenes,has been investigated under the irradiation of ultrasound and ultravioletlight respectively and simultaneously.It is found that the degradation of AO7 in solution occurs under the irradiation of ultrasound or ultraviolet,in which the reaction process for the AO7 degradation shows a pseudo-first order kinetics.The same reaction kinetics is found for the degradation of AO7 under the combined ultrasound and ultraviolet.We further have found that the degradation efficiency for AO7 under the combined irradiation of ultrasound and ultraviolet is larger than the sum of that under the respective irradiations of ultrasound and ultraviolet light,indicating a synergistic effect of ultrasound and ultraviolet light irradiations.Based on the analysis of the reaction kinetics,the synergistic effect could be ascribed to the ultraviolet induced decomposition of hydrogen peroxide (H2O2).